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Synthesis and crystal structure of ((NH3CH2CH2)3N)2P6O18·6H2O

Identifieur interne : 001A12 ( Main/Exploration ); précédent : 001A11; suivant : 001A13

Synthesis and crystal structure of ((NH3CH2CH2)3N)2P6O18·6H2O

Auteurs : H. Marouani [Tunisie] ; M. Rzaigui [Tunisie]

Source :

Solid State Sciences [ 1293-2558 ] ; 1999.

RBID : ISTEX:1388D5A24423B5FC394062C7678BB89352E53E1B

English descriptors

Teeft :
- Anion, Atomic arrangement, Bond angles, Chem, Crystal structure, Direct method, Hydrogen atoms, Hydrogen bonds, Internal symmetry, Marouani, Powder data, Regular hexagon, Ring anions, Rzaigui, Solid state sciences, Standard deviations, Tetrahedron, Title compound, Tome, Unit cell parameters, Water molecules.

Abstract

Abstract: Chemical preparation and crystal structure are given for a new cyclohexaphosphate: ((NH3CH2CH2)3N)2P6O18·6H2O. This compound is triclinic P¯1 with the following unit-cell parameters: a = 10,281(1)Å, b = 11.083(1)Å, c = 9.307(2)Å, α = 103.83(1) °, β = 108.56(1) °, γ = 68.11(1) °, Z = 1, V = 924.2(3)Å3 and pcal. = 1.582 g.cm−3. Its atomic arrangements contain layers built by P6O18 ring anions spreading in the plans (001). Between these layers are located the organic groups which form hydrogen bonds with oxygen atoms of P6O18 rings and water molecules. Crystal structure has been solved and refined to R = 0.028 using 4540 independent reflections. The thermal behavior has been investigated and interpreted by comparison with IR absorption spectroscopy and X-ray diffraction experiments.

Url:

https://api.istex.fr/ark:/67375/6H6-93JX7V3Q-6/fulltext.pdf

DOI: 10.1016/S1293-2558(00)80093-X

Affiliations:

Tunisie

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Le document en format XML

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<front><div type="abstract" xml:lang="en">Abstract: Chemical preparation and crystal structure are given for a new cyclohexaphosphate: ((NH3CH2CH2)3N)2P6O18·6H2O. This compound is triclinic P¯1 with the following unit-cell parameters: a = 10,281(1)Å, b = 11.083(1)Å, c = 9.307(2)Å, α = 103.83(1) °, β = 108.56(1) °, γ = 68.11(1) °, Z = 1, V = 924.2(3)Å3 and pcal. = 1.582 g.cm−3. Its atomic arrangements contain layers built by P6O18 ring anions spreading in the plans (001). Between these layers are located the organic groups which form hydrogen bonds with oxygen atoms of P6O18 rings and water molecules. Crystal structure has been solved and refined to R = 0.028 using 4540 independent reflections. The thermal behavior has been investigated and interpreted by comparison with IR absorption spectroscopy and X-ray diffraction experiments.</div>
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Synthesis and crystal structure of ((NH3CH2CH2)3N)2P6O18·6H2O

Synthesis and crystal structure of ((NH3CH2CH2)3N)2P6O18·6H2O

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

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